What are intumescent paints made of?
Ablative intumescent coatings have a large number of hydrates in them; when hydrates are heated (in a fire), they break down, and the water vapour is released, which has a cooling effect. When the water has fully evaporated, the material left behind is known as CHAR. Depending on the application of the paint used, there are two types of Char, soft and hard.
Let’s look at soft or light char; this is typically used in thin-film applications of passive protection and comprises a microporous carbonaceous foam formed by a chemical reaction. The chemicals are Melamine, Pentaerythritol and Ammonium polyphosphate. For the reaction to occur, it needs a molten binder, typically a vinyl acetate copolymer or styrene acrylates. When the paint is heated to the right temperature, the paint expands up to 50 times its size, forming the char and this foamlike structure insulating the structural steel. The pressure from the expansion is low as its job is to create a protective layer over the item. This slows down the heat transfer and extends the amount of time the item is stable for.
Hard Char is like soft char in its makeup, but sodium silicates and graphite are added to make it fast and more robust in the expansion stage, but it only expands to 5 times its size. When applied to plastic pipes, it can be used as a fire stop as its aggressive expansion can squash the pipe and shut off any route for the fire to spread in the pipe. Hard Char products are typically used in exterior applications and are unsuitable for interior spray fireproofing.
What is the British Standard for intumescent paint?
Intumescent coatings for steel constructions must be approved in standardised fire tests. the British Standard is BS 476-20/21, and the European Union is EN 13381-8